Studying the Influence of the Load Profile Changes on the Stack Performance Based on the Fuel Cells with a Proton Exchange Membrane
DOI:
https://doi.org/10.17213/0136-3360-2022-4-25-30Keywords:
hydrogen, fuel cells, PEM, durability, degradationAbstract
The effect of transitions from low power to high power on the output characteristics of a stack based on proton-exchange membrane fuel cells (PEMFC) is considered. The operation of the PEMFC stack in transient operating conditions in the on/off modes and a gradual increase in power with subsequent shutdown is analyzed. 40 % reduction in maximum power during continuous operation in the on / off mode and an 8 % reduction in power in the mode of gradual increase in power with subsequent shutdown being shown. It has been established that different degradation rates can be associated with some factors influence or their combination, including the time of operation at no-load voltage, the time of operation at maximum power, and the energy throughput per unit time. The power plant operation scheme on PEMFC is presented, which allows to withstand the cyclic change of operating modes, while smoothing out the negative consequences of transient modes.
References
Popel O.S., Tarasenko A.B., Filippov S.P. Fuel cell based power-generating installations: State of the art and future prospects //Thermal Engineering. 2018. Т. 65. №. 12. С. 859 – 874. https://doi.org/10.1134/S0040601518120078
Pan Z.F., An L., Wen C.Y. Recent advances in fuel cells based propulsion systems for unmanned aerial vehicles //Applied Energy. 2019. Т. 240. С. 473 – 485. https://doi.org/10.1016/j.apenergy.2019.02.079
Bethoux O. Hydrogen Fuel Cell Road Vehicles: State of the Art and Perspectives // Energies. 2020. Т. 13. №. 21. С. 5843. https://doi.org/10.3390/en13215843
Chen H., Song Z., Zhao X., Zhang T., Pei P., & Liang C. A review of durability test protocols of the proton exchange membrane fuel cells for vehicle // Applied energy. 2018. Т. 224. С. 289 – 299. https://doi.org/10.1016/j.apenergy.2018.04.050
Fuel Cell Technical Team Roadmap. Available online: https://www.energy.gov/sites/prod/files/2017/11/f46/FCTT_ Roadmap_Nov_2017_FINAL.pdf (accessed on 1 February 2021).
Wang Y., Diaz D. F.R., Chen K.S., Wang Z., & Adroher X.C. Materials, technological status, and fundamentals of PEM fuel cells–a review // Materials today. 2020. Т. 32. С. 178 – 203. https://doi.org/10.1016/j.mattod.2019.06.005
Fuel Cells Section. In Multi-Year Research, Development, and Demonstartion Plan; U.S. Department of Energy: Wash-ington, DC, USA, 2015; pp. 1 – 58.
Пат. 2 748 853 РФ МПК H01M 8/02, H01M 8/0202. Биполярная пластина топливного элемента с твердым полимерным электролитом и способ ее изготовления / Смирнова Н.В., Фаддеев Н.А., Горчаков В.В.
Leontyev I. et al. New life of a forgotten method: Electrochemical route toward highly efficient Pt/C catalysts for low-temperature fuel cells //Applied Catalysis A: General. 2012. Т. 431. С. 120 – 125. https://doi.org/10.1016/j.apcata.2012.04.025
FCTESTNET Test Module TM PEFC SC 5-7, Version 30 04; JRC Scientific and Technical Publications Office of the European Union: Luxembourg, 2010.
Nguyen H.L. et al. Review of the durability of polymer electrolyte membrane fuel cell in long-term operation: main influencing parameters and testing protocols //Energies. 2021. Т. 14. №. 13. С. 4048. https://doi.org/10.3390/en14134048
Aarhaug T.A., Svensson A.M. Degradation rates of PEM fuel cells running at open circuit voltage // ECS Transac-tions. 2006. Т. 3. № 1. С. 775. https://doi.org/10.1149/1.2356197
Bloom I., Walker L., Basco J., Malkow T., De Marco G., & Tsotridis G. A comparison of fuel cell test protocols // ECS Transactions. 2011. Т. 30. №. 1. С. 227. https://doi.org/10.1149/1.3562478
Borup, R., Meyers, J., Pivovar, B., Kim, Y. S., Mukundan, R., Garland. Scientific aspects of polymer electrolyte fuel cell durability and degradation // Chemical reviews. 2007. Т. 107. № 10. С. 3904 – 3951. https://doi.org/10.1021/cr050182l
Васюков И.В. Компьютерные модели топливного элемента с протонообменной мембраной для исследования переходных режимов в электротехнических комплексах энергетических установок // Изв. вузов. Электромеханика. 2021. Т. 64. № 3. С. 60 – 67. https://doi.org/ https://doi.org/10.17213/0136-3360-2021-3-60-67.
Васюков И.В., Павленко А.В., Батищев Д.В. Обзор и анализ топологий преобразователей систем электропитания на водородных топливных элементах для беспилотных летательных аппаратов киловаттного класса мощности // Изв. вузов. Электромеханика. 2022. Т. 65. № 2. С. 19 – 26. https://doi.org/10.17213/0136-3360-2022-2-19-26.